EnergyCrystals

From Hackteria Wiki
Jump to: navigation, search

This page is to summarize our research in electro active crystal materials. There are many great instructions and descriptions online. The purpose of this summary is to give an overview of what we looked into and interesting insights we found. For detailed step by step instructions follow the links.

There are different electro active effects in crystal materials and those effects can be viewed in an onion hierarchy in some materials cumulate multiple effects.

Crystal electric effects.jpg


Dielectric Effect

The most basic effect is the dielectric effect. When an electric field is applied by placing electrodes on two surfaces of crystals and applying an electric voltage, the crystal polarizes (dielectric polarisation). This means, while the crystals are electrically isolating materials and no current can flow through, in dielectric materials, charges can still shift slightly towards the poles.

What is this good for? Don't know, it's just the effect highest in hierarchy.

Piezoelectric Effect

Much more interesting is piezoelectric effect, the next in the hierarchy. All piezoelectric materials are also dielectric materials (while not all dielectric materials are also piezoelectric). A piezoelectric material has a special internal charge distribution such that when a mechanical force or vibration is applied it generates a polarization. So when the piezoelectric crystal with two conducive surfaces is put under mechanical stress it generates and electric voltage. This effect is reversible, so when an electric voltage is applied the crystal may deform.

Pyroelectric Effect

It get's even more fancy with the pyroelectric effect where a change in temperature can create an electric charge. And again, every pyroelectric crystal is also piezoelectric and dielectric.

We have not gone into this effect much yet.

Ferroelectric Effect

Deepest down in the amazing electro active effects of crystals materials are the ferroelectric materials. If you find those you are lucky, they combine all the previous effects, plus they can keep their electric polarization even when the applied voltage is removed. So by that effect the crystals can be "programmed" to store information. Yes, see the experiments described below.

By the way, already Pierre and Jacques Curie experimented with the piezoelectric effect and found that quartz and Rochelle salt display the strongest piezoelectricity. But this time they were not the first to discover the effect itself it was discovered in 1824 by David Brewster.

Today we know that even onion skin, DNA, phages and maybe even candy floss made from cane sugar shows piezzoelectric effects.

Make Rochelle Salt Crystals

Making crystals is easy and fun. An easy way to grow nice crystals is with Potassium alum. All ready the ancient Egyptians used it to make crystals. However while Potassium alum is dielectric, it is not piezoelectric.

An easy to grow crystal that shows all the amazing electro active properties is Rochelle Salt crystal. Also know as Sodium Potassium Tartrate Tetrahydrate, the crystals can be grown with common kitchen ingredients. All you need is washing soda (sodium carbonate), cream of tartar (potassium bitartrate or potassium hydrogen tartrate), and water. If you don't find washing soda you can make it from baking soda. See instructions blow.

Here just our learnings form spending hours of trying to make big and perfect crystals:

  • While there are slightly different recipes, the ratio of water and cream of tartar should be somewhere between 1.25x and 1.38
  • The ratio between cream of tartar and sodium carbonate is about 3.8x but this is not so important as you just add as much soda until it stops fizzling
  • Yes, adding sodium slowly seems to be important, especially towards the end
  • The solubility changes a lot with the temperature. So make sure you are at about 70°C
  • The crystals start forming as the solution cools down. If the concentration is too high crystals form too quickly and you get just many small crystals
  • If the concentration is too low the seed crystals dissolve before they start to grow. So getting the concentration right is important.
  • Rochelle Salt crystals dissolve easily in water. So if you are not happy with what you get, a good way is to just dissolve the Rochelle Salt again and make it crystallize again.
  • Seed crystals are an art on it's own. Suspend a perfectly formed seed crystal in the cooled down solution to grow big and perfect crystals.
  • To attach seed crystals to a wire a good method we found is to heat a thin cooper wire and stick it into the crystal (by locally melting it)
  • Yes, Rochelle Salt Crystals have a very low melting point of about 75°C
  • The low melting property can be used to easily make multi-crystalline materials
  • Sodium hydroxide (NaOH) can be used instead of Washing soda
  • The Rochelle Salt Crystals have a very distinct crystal shape. You see it if you grow a perfect crystal
  • The different electric effects vary with the face of the crystal you apply the electrodes to



BigCrystal.jpg

Links:
https://www.instructables.com/Make-Rochelle-Salt/
https://sciencenotes.org/how-to-make-rochelle-salt-sodium-potassium-tartrate-tetrahydrate/
https://en.wikipedia.org/wiki/Potassium_bitartrate
http://dmishin.blogspot.com/2014/11/crystal-growing-rochelle-salt.html

Hearing the crystals with a NanoAmp

The electric charges created by a piezoelectric crystal can be heard through an audio amplifier. With the NanoAmp by the Swiss Mechatronic Art Society (SGMK) we could hear vibrations on our self grown Rochel Salt Crystals. With two electrodes applied to the crystals and attached to the imput of the amplifier, tapping on the crystal can be clearly heard through a headphone. Even just scratching the crystals with one input lead while holding the other one to the crystal, scratchy sounds appear. This method can also be used to distinguish crystals made from piezoelectric and non-piezoelectric materials (such as alum crystals)
NanoAmpCrystal.jpg

NanoAmp.jpg

File:NanoAmp_MakeAway.pdf

Measuring with a Charge Amplifier

A scientific way to measure the piezoelectric effect of materials is to use a so called charge amplifier. This type of amplifier has a very high input resistance and a high amplification. When connected to a material that generates electric charges the circuit produces a signal that can displayed.

For our first experiments we built the circuit described in Teet Kivirand Master’s Thesis "METHOD FOR MEASURING PIEZOELECTRIC CHARGE COEFFICIENTS" (see link).


ChargeAmplifier.jpg


https://digikogu.taltech.ee/en/Download/7a73bb81-54e9-4443-b2bc-2e3d58bcacad

Making Crystals Sing with a Signal Generator

Piezoelectric materials contract and expand when electric voltages are a applied to them. This property is used in piezzo speakers and buzzers that are used in many everyday devices such as beeping clocks or buzzing microwave ovens or funny sounding toys. To make these sounds, an alternating voltage at audible frequency has to be applied to two electrodes on the crystal. We used a signal generator to generate these voltages and trying to hear the crystals sing. The signal generator was set to its highest voltage of 20V and a square waveform was chosen. We found that higher frequencies of 15-20 kHz worked best even though these frequencies require a young ear to be heard. We successfully made sing big rose quartz crystals and other self grown crystals.

SignalGeneratorCrystals.jpg

Storing charge on a Rochelle Salt crystal

Making Amorphous Crystals

Sparkles on commercial piezo element